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PPE (Polyphenyl ether)

Chemical name: Poly(2,6-dimethyl-1,4-phenylene ether)

Synonyms: PPE, PPO, Polyphenylene Oxide, Poly(2,6-dimethylphenylene oxide)

CAS: 25134-01-4

Molecular formula: (C8H9O)n

Specification / COA:

ItemStandardCOA
AppearanceBrown granuleComplies
HEW (g/eq)950 max860
Mn Weight (g/mol)1700-21001840
PDI1.9-2.32.07
Toluene Residue1.5% max0.5%

Usage:

  • High-frequency, high-speed copper-clad laminates (CCL): PPE’s exceptionally low dielectric constant (Dk 2.5-2.8) and low loss tangent (Df below 0.005) make it the preferred resin matrix for high-frequency CCL used in 5G infrastructure, radar systems, and millimetre-wave applications
  • 5G communication base stations and antennas: Used in antenna substrates, power amplifier boards, and backplane laminates where signal integrity at mmWave frequencies is critical
  • Automotive electronics: ADAS radar modules, infotainment PCBs, and advanced driver-assistance systems benefit from PPE’s thermal stability (Tg above 200 degrees C) and dimensional stability under underhood conditions
  • High-speed digital circuit boards: Server backplanes, high-bandwidth memory modules, and AI accelerator boards requiring low-loss signal transmission at 56 Gbps and beyond
  • Aerospace and defence: Phased-array radar substrates and satellite communication boards where stable dielectric properties across wide temperature ranges are essential
  • Reactive epoxy blending: Hydroxy-capped PPE (HEW 860 g/eq) is co-cured with epoxy resins and curing agents to significantly lower Dk/Df of conventional FR-4 formulations while improving thermal performance

Packing: 25 kg per fibre drum or carton box with PE inner liner; customised packaging available on request.

Storage: Store in a cool, dry, well-ventilated area away from moisture and direct sunlight. Keep containers tightly sealed. Recommended shelf life: 12 months from manufacturing date.

Related Products

Further Reading: PPE Resin for High-Frequency CCL: Rising Demand and China Alternatives

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PPE (Polyphenyl ether) is a high-performance engineering resin valued for its outstanding dielectric properties, which remain stable across a broad frequency range from MHz to GHz. The hydroxy-terminated PPE oligomer (HEW at most 950 g/eq) is designed specifically for reactive blending with epoxy or cyanate ester systems, enabling formulators to produce next-generation CCL (copper-clad laminate) with Dk values below 3.0 and Df below 0.005 — critical requirements for 5G and high-speed PCB applications. The narrow molecular weight distribution (PDI 1.9-2.3, Mn 1700-2100 g/mol) ensures consistent cross-link density and predictable thermal performance. Automotive-grade applications exploit PPE’s inherent dimensional stability and resistance to hydrolysis, ensuring reliable signal performance in harsh underhood environments. Unifarm Chemical supplies this hydroxy-functional PPE grade from qualified manufacturers in China with full batch traceability and COA documentation.

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